475649-32-2

• 

• Basic information

  1. Product Name: D-4'-TETRAHYDROPYRANYLGLYCINE
  2. Synonyms: 2H-Pyran-4-aceticacid,alpha-aminotetrahydro-,(alphaR)-(9CI);(R)-2-amino-2-(tetrahydro-2H-pyran-4-yl)acetic acid;REF DUPL: D-4'-Tetrahydropyranylglycine;2H-Pyran-4-acetic acid, .alpha.-aminotetrahydro-, (.alpha.R)-;(alphaR)-alpha-Aminotetrahydro-2H-pyran-4-acetic acid;2H-Pyran-4-acetic acid, α-aminotetrahydro-, (αR)-;(R)-a-Aminotetrahydro-2H-pyran-4-acetic acid;EOS-61298
  3. CAS NO:475649-32-2
  4. Molecular Formula: C7H13NO3
  5. Molecular Weight: 159.19
  6. EINECS: N/A
  7. Product Categories: GLYCINESCAFFOLD
  8. Mol File: 475649-32-2.mol

• Chemical Properties

  1. Melting Point: N/A
  2. Boiling Point: 316.7°C at 760 mmHg
  3. Flash Point: 145.3°C
  4. Appearance: /
  5. Density: 1.211
  6. Vapor Pressure: 8.62E-05mmHg at 25°C
  7. Refractive Index: 1.505
  8. Storage Temp.: Sealed in dry,Room Temperature
  9. Solubility: N/A
  10. PKA: 2.25±0.10(Predicted)
  11. CAS DataBase Reference: D-4'-TETRAHYDROPYRANYLGLYCINE(CAS DataBase Reference)
  12. NIST Chemistry Reference: D-4'-TETRAHYDROPYRANYLGLYCINE(475649-32-2)
  13. EPA Substance Registry System: D-4'-TETRAHYDROPYRANYLGLYCINE(475649-32-2)

• Safety Data

  1. Hazard Codes: N/A
  2. Statements: N/A
  3. Safety Statements: N/A
  4. WGK Germany:
  5. RTECS:
  6. HazardClass: N/A
  7. PackingGroup: N/A
  8. Hazardous Substances Data: 475649-32-2(Hazardous Substances Data)

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• Downstream Products
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475649-32-2 Usage

Uses

Used in Pharmaceutical Industry:
D-4'-Tetrahydropyranylglycine is used as a protective group for the carboxylic acid functional group during the synthesis of various pharmaceuticals and bioactive compounds. Its application ensures that the carboxylic acid remains intact and unreacted while other functional groups within the molecule are selectively manipulated, facilitating the successful synthesis of the desired compounds.

Check Digit Verification of cas no

The CAS Registry Mumber 475649-32-2 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 4,7,5,6,4 and 9 respectively; the second part has 2 digits, 3 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 475649-32:
(8*4)+(7*7)+(6*5)+(5*6)+(4*4)+(3*9)+(2*3)+(1*2)=192
192 % 10 = 2
So 475649-32-2 is a valid CAS Registry Number.

InChI:InChI=1/C7H13NO3/c8-6(7(9)10)5-1-3-11-4-2-5/h5-6H,1-4,8H2,(H,9,10)

475649-32-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name	(R)-2-Amino-2-(tetrahydro-2H-pyran-4-yl)acetic acid

1.2 Other means of identification

Product number	-
Other names	(2R)-2-amino-2-(oxan-4-yl)acetic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses	For industry use only.
Uses advised against	no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number	-
Service hours	Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:475649-32-2 SDS

475649-32-2Upstream product

• 871261-02-8 2-oxo-2-(tetrahydro-2H-pyran-4-yl)acetic acid 
• 861160-58-9 C₉H₁₄O₄ 
• 5337-03-1 tetrahydro-2H-pyran-4-carboxylic acid 
• 50675-18-8 3,4,5,6-tetrahydro-2H-pyran-4-carbaldehyde 
• 151-50-8 potassium cyanide 

475649-32-2Downstream Products

• 889949-63-7 2-amino-2-(tetrahydro-2H-pyran-4-yl)ethanol 

475649-32-2Relevant articles and documents

SYNTHESIS METHOD FOR L-CYCLIC ALKYL AMINO ACID AND PHARMACEUTICAL COMPOSITION HAVING THEREOF

-

Paragraph 0090; 0097, (2016/11/17)

A synthesis method for L-cyclic alkyl amino acid and a pharmaceutical composition having the said amino acid are provide in the present disclosure provides. The synthesis method comprises: step A.) preparing a cyclic alkyl keto acid or a cyclic alkyl keto acid salt having Structural Formula (I) or Structural Formula (II), and step B.) mixing the cyclic alkyl keto acid or the cyclic alkyl keto acid salt with ammonium formate, a leucine dehydrogenase, a formate dehydrogenase and a coenzyme NAD+, and carrying out a reductive amination reaction to generate the L-cyclic alkyl amino acid, wherein the Structural Formula (I) is where n1≧1, m1≧0 and the M1 is H or a monovalent cation; the Structural Formula (II) is where n2≧0, m2≧0, the M2 is H or a monovalent cation, an amino acid sequence of the leucine dehydrogenase is SEQ ID No.1.

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